Inferences about the likely physical and chemical nature of fluids at
temperatures and pressures above the critical point of water (CPW) come from
studies of hydrothermal ore deposits related to shallow magmatic intrusions,
from studies of metamorphic rocks, and from results of laboratory experiments
investigating (1) mechanical properties of rocks, (2) fluid-mineral reactions, and
(3) PVT characteristics of brines and gases. Fluid pressures that are likely to be
encountered at drillable depths where temperatures are above the CPW are
greatly influenced by the transition from brittle to plastic behavior of rock. This
occurs at about 400°C in silica-rich rocks in tectonically active regions (assumed
strain rate 10-14 sec-1). In contrast, in basaltic rocks the transition from brittle
to plastic behavior occurs at about 500° to 600°C. Thus, seismicity that opens
new fractures and reopens old fractures that have become clogged by mineral
deposition can occur at much higher temperatures in basaltic rocks than in silicic
rocks.
A second important factor is self-sealing of fractures by mineral
deposition that appears to occur very rapidly in most rocks at about 400°C.
Aqueous-rich fluids and gases evolved from crystallizing magma and/or by
metamorphic reactions, tend to become trapped beneath this self-sealed zone
at greater than hydrostatic pressure. In rocks that behave plastically, and
where the least principal stress is the lithostatic load, the mechanically most
stable configuration for brine and coexisting gas is in flat-lying sheets or
discontinuous lenses at or near lithostatic pressure. However, many
epithermal ore deposits appear to have formed where there has been episodic
rapid movement of substantial quantities of fluids from the high-temperature,
high-pressure plastic region across the self-sealed zone into lower-
temperature brittle rock. In this process brecciation of rock occurs adjacent to
channels of flow in the shallower and cooler brittle region.
Saline fluids above the CPW evolve to mixtures of hypersaline brine
and coexisting gas. The brine becomes more saline and the coexisting gas less
saline either as temperature increases or as pressure decreases. Brecciation
occurs in the plastic source region where “boiling” of brine and expansion of
gas are induced by a temporary drop in fluid pressure that occurs as the gas,
or a froth of brine and gas, moves rapidly through breaches in a self-sealed
zone. A continued decrease in pressure results in the system entering a field
of gas plus solid salt. In this region significant concentrations of HCl° tend to
be generated by hydrolysis of the precipitated salts. However, the HCl° is a
highly associated species which is non-reactive. It becomes dissociated and
reactive only where the gas moves into a cooler environment and liquid water
condenses.
Above the CPW non-condensable gases, such as CO2, H2S, and SO2
strongly partition into the “steam” phase coexisting with brine. With
decreasing pressure the SO2/H2S ratio in the vapor phase exsolved from a
crystallizing magma increases. Thus, volcanic gases tend to be relatively rich in
SO2. However, underground, as a hydrothermal system cools, SO2 reacts with
water and with the surrounding rock producing H2S and sulfates.
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